To charge a LiFePO4 battery safely, use a LiFePO4 CC/CV profile, set the correct voltage for your series cell count, limit charge current to the battery rating, and stop when current tapers to a small tail. Avoid charging at or below 0°C, and avoid continuous float. Charging a LiFePO4 (lithium iron phosphate) battery seems straightforward, but there are some important details you need to know to do it safely and effectively. To ensure your battery remains in top condition for as long as possible, it's crucial to know how to charge a LiFePO4 battery correctly. This not only optimizes performance but also protects your investment. In this guide, I'll. When the LFP battery is charged, lithium ions migrate from the surface of the lithium iron phosphate crystal to the surface of the crystal.