Here, we designed a nanostructured carbon layer to suppress the diffusion of ions/molecules within perovskite solar cells, an important degradation process in the device.
Hysteresis in current–voltage curves has been an important issue for conversion efficiency evaluation and development of perovskite solar cells (PSCs). In this study, we explored the ion diffusion effects in tetragonal CH 3 NH 3 PbI 3 (MAPbI 3) and trigonal (NH 2) 2 CHPbI 3 (FAPbI 3) by first-principles calculations.
Understating degradation pathways is critical to the development of perovskite photovoltaics. Thiesbrummel et al. show that internal electric field screening induced by ion migration is a dominant contributor to the operational performance loss of perovskite solar cells.
Thiesbrummel, J. et al. Universal current losses in perovskite solar cells due to mobile ions. Adv. Energy Mater. 11, 2101447 (2021). Cave, J. M. et al. Deducing transport properties of mobile vacancies from perovskite solar cell characteristics. J. Appl. Phys. 128, 184501 (2020).
The doped device delivers a higher power conversion efficiency (PCE) of 21.31% together with improved ambient stability in comparison with the control device (PCE = 19.26%). This work demonstrates a simple and effective ion diffusion-induced double layer by chemical doping strategy to advance the development of perovskite photovoltaics.
Ghasemi, M. et al. A multiscale ion diffusion framework sheds light on the diffusion–stability–hysteresis nexus in metal halide perovskites. Nat. Mater. 22, 329–337 (2023). Zu, F. et al. Position-locking of volatile reaction products by atmosphere and capping layers slows down photodecomposition of methylammonium lead triiodide perovskite.
Additionally, our results show that the activation energy of halide diffusion in the volume (EV) ranges from 0.61 eV for the bromide ion (Br −) diffusion in MAPbI 3 to a maximum of 0.74 eV for the iodide ion (I −) diffusion in FAPbBr 3, in good agreement with prior reports for halide diffusion activation energy 18.
To adequately estimate the performance of a photovoltaic panel (PV) under actual field conditions, the present study tackles this problem by a multi-physics approach, where a thermal model based on a 3.
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